Interactions of Binary Mixtures of 1-Methyl-3-Phenylimidazolium Iodide [MPhlm][l] and Isopropyl Alcohol [C<sub>3</sub>H<sub>8</sub>O] at Varying Temperatures

Victoria Bennett; Nimibofa Ayawei

doi:doi:10.11648/j.ajpc.20221103.11

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Interactions of Binary Mixtures of 1-Methyl-3-Phenylimidazolium Iodide [MPhlm][l] and Isopropyl Alcohol [C₃H₈O] at Varying Temperatures

Victoria Bennett, Nimibofa Ayawei

Published in American Journal of Physical Chemistry (Volume 11, Issue 3)

Received: 9 July 2022 Accepted: 8 August 2022 Published: 17 August 2022

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Abstract

In potential engineering and process design applications of binary mixtures containing ionic liquids (ILs), the accurate determination of the physiochemical properties plays a pertinent role. Thermodynamic studies can provide an understanding into the nature of intermolecular interactions occurring between the solute and solvent in solutions. To this effect, thermodynamic properties of binary mixtures of 1-Methyl-3-Phenylimidazolium Iodide [MPhlM][l] + Isopropyl Alcohol [C₃H₈O] have been studied over the concentration range of mole fraction 0–1. Density and viscosity of the pure ionic liquid (IL) and the binary systems were measured and calculated. These data have been used to calculate excess molar volumes, VmE, Excess viscosity, Δη, excess Gibbs free energy of activation of viscous flow, ∆G*E of each component in the mixtures. To derive the binary coefficients and the standard deviations, the results were fitted into the Redlich-Kister Polynomial equation. The experimental and calculated quantities were used to study the nature of intermolecular interactions between the binary mixtures of 1-Methyl-3-Phenylimidazolium Iodide [MPhlM][l] + Isopropyl Alcohol [C₃H₈O]. Several factors were discovered to have influenced the interactions. Positive excess molar volume (VmE) values reported were influenced by dipole-dipole and dipole-dipole induced interactions between unlike molecules, resulting in the contraction of the molar volumes of the mixtures. The viscosities were correlated with single parameter Grungberg-Nissan, Hind, Frenkel and Kendel- Monroe models.

Published in	American Journal of Physical Chemistry (Volume 11, Issue 3)
DOI	10.11648/j.ajpc.20221103.11
Page(s)	45-51
Creative Commons	This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.
Copyright	Copyright © The Author(s), 2024. Published by Science Publishing Group

Keywords

Molecular Interaction, Density, Excess Viscosity

References

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APA Style

Victoria Bennett, Nimibofa Ayawei. (2022). Interactions of Binary Mixtures of 1-Methyl-3-Phenylimidazolium Iodide [MPhlm][l] and Isopropyl Alcohol [C3H8O] at Varying Temperatures. American Journal of Physical Chemistry, 11(3), 45-51. https://doi.org/10.11648/j.ajpc.20221103.11

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ACS Style

Victoria Bennett; Nimibofa Ayawei. Interactions of Binary Mixtures of 1-Methyl-3-Phenylimidazolium Iodide [MPhlm][l] and Isopropyl Alcohol [C3H8O] at Varying Temperatures. Am. J. Phys. Chem. 2022, 11(3), 45-51. doi: 10.11648/j.ajpc.20221103.11

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AMA Style

Victoria Bennett, Nimibofa Ayawei. Interactions of Binary Mixtures of 1-Methyl-3-Phenylimidazolium Iodide [MPhlm][l] and Isopropyl Alcohol [C3H8O] at Varying Temperatures. Am J Phys Chem. 2022;11(3):45-51. doi: 10.11648/j.ajpc.20221103.11

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@article{10.11648/j.ajpc.20221103.11,
  author = {Victoria Bennett and Nimibofa Ayawei},
  title = {Interactions of Binary Mixtures of 1-Methyl-3-Phenylimidazolium Iodide [MPhlm][l] and Isopropyl Alcohol [C3H8O] at Varying Temperatures},
  journal = {American Journal of Physical Chemistry},
  volume = {11},
  number = {3},
  pages = {45-51},
  doi = {10.11648/j.ajpc.20221103.11},
  url = {https://doi.org/10.11648/j.ajpc.20221103.11},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajpc.20221103.11},
  abstract = {In potential engineering and process design applications of binary mixtures containing ionic liquids (ILs), the accurate determination of the physiochemical properties plays a pertinent role. Thermodynamic studies can provide an understanding into the nature of intermolecular interactions occurring between the solute and solvent in solutions. To this effect, thermodynamic properties of binary mixtures of 1-Methyl-3-Phenylimidazolium Iodide [MPhlM][l] + Isopropyl Alcohol [C3H8O] have been studied over the concentration range of mole fraction 0–1. Density and viscosity of the pure ionic liquid (IL) and the binary systems were measured and calculated. These data have been used to calculate excess molar volumes, VmE, Excess viscosity, Δη, excess Gibbs free energy of activation of viscous flow, ∆G*E of each component in the mixtures. To derive the binary coefficients and the standard deviations, the results were fitted into the Redlich-Kister Polynomial equation. The experimental and calculated quantities were used to study the nature of intermolecular interactions between the binary mixtures of 1-Methyl-3-Phenylimidazolium Iodide [MPhlM][l] + Isopropyl Alcohol [C3H8O]. Several factors were discovered to have influenced the interactions. Positive excess molar volume (VmE) values reported were influenced by dipole-dipole and dipole-dipole induced interactions between unlike molecules, resulting in the contraction of the molar volumes of the mixtures. The viscosities were correlated with single parameter Grungberg-Nissan, Hind, Frenkel and Kendel- Monroe models.},
 year = {2022}
}

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TY  - JOUR
T1  - Interactions of Binary Mixtures of 1-Methyl-3-Phenylimidazolium Iodide [MPhlm][l] and Isopropyl Alcohol [C3H8O] at Varying Temperatures
AU  - Victoria Bennett
AU  - Nimibofa Ayawei
Y1  - 2022/08/17
PY  - 2022
N1  - https://doi.org/10.11648/j.ajpc.20221103.11
DO  - 10.11648/j.ajpc.20221103.11
T2  - American Journal of Physical Chemistry
JF  - American Journal of Physical Chemistry
JO  - American Journal of Physical Chemistry
SP  - 45
EP  - 51
PB  - Science Publishing Group
SN  - 2327-2449
UR  - https://doi.org/10.11648/j.ajpc.20221103.11
AB  - In potential engineering and process design applications of binary mixtures containing ionic liquids (ILs), the accurate determination of the physiochemical properties plays a pertinent role. Thermodynamic studies can provide an understanding into the nature of intermolecular interactions occurring between the solute and solvent in solutions. To this effect, thermodynamic properties of binary mixtures of 1-Methyl-3-Phenylimidazolium Iodide [MPhlM][l] + Isopropyl Alcohol [C3H8O] have been studied over the concentration range of mole fraction 0–1. Density and viscosity of the pure ionic liquid (IL) and the binary systems were measured and calculated. These data have been used to calculate excess molar volumes, VmE, Excess viscosity, Δη, excess Gibbs free energy of activation of viscous flow, ∆G*E of each component in the mixtures. To derive the binary coefficients and the standard deviations, the results were fitted into the Redlich-Kister Polynomial equation. The experimental and calculated quantities were used to study the nature of intermolecular interactions between the binary mixtures of 1-Methyl-3-Phenylimidazolium Iodide [MPhlM][l] + Isopropyl Alcohol [C3H8O]. Several factors were discovered to have influenced the interactions. Positive excess molar volume (VmE) values reported were influenced by dipole-dipole and dipole-dipole induced interactions between unlike molecules, resulting in the contraction of the molar volumes of the mixtures. The viscosities were correlated with single parameter Grungberg-Nissan, Hind, Frenkel and Kendel- Monroe models.
VL  - 11
IS  - 3
ER  -

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Author Information

Victoria Bennett

Department of Chemical Sciences, Faculty of Basic and Applied Sciences, University of Africa, Toru-Orua, Sagbama, Nigeria
Nimibofa Ayawei

Department of Chemistry, Faculty of Science, Medical University, Yenagoa, Nigeria

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Victoria Bennett, Nimibofa Ayawei. (2022). Interactions of Binary Mixtures of 1-Methyl-3-Phenylimidazolium Iodide [MPhlm][l] and Isopropyl Alcohol [C3H8O] at Varying Temperatures. American Journal of Physical Chemistry, 11(3), 45-51. https://doi.org/10.11648/j.ajpc.20221103.11

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ACS Style

Victoria Bennett; Nimibofa Ayawei. Interactions of Binary Mixtures of 1-Methyl-3-Phenylimidazolium Iodide [MPhlm][l] and Isopropyl Alcohol [C3H8O] at Varying Temperatures. Am. J. Phys. Chem. 2022, 11(3), 45-51. doi: 10.11648/j.ajpc.20221103.11

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AMA Style

Victoria Bennett, Nimibofa Ayawei. Interactions of Binary Mixtures of 1-Methyl-3-Phenylimidazolium Iodide [MPhlm][l] and Isopropyl Alcohol [C3H8O] at Varying Temperatures. Am J Phys Chem. 2022;11(3):45-51. doi: 10.11648/j.ajpc.20221103.11

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@article{10.11648/j.ajpc.20221103.11,
  author = {Victoria Bennett and Nimibofa Ayawei},
  title = {Interactions of Binary Mixtures of 1-Methyl-3-Phenylimidazolium Iodide [MPhlm][l] and Isopropyl Alcohol [C3H8O] at Varying Temperatures},
  journal = {American Journal of Physical Chemistry},
  volume = {11},
  number = {3},
  pages = {45-51},
  doi = {10.11648/j.ajpc.20221103.11},
  url = {https://doi.org/10.11648/j.ajpc.20221103.11},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajpc.20221103.11},
  abstract = {In potential engineering and process design applications of binary mixtures containing ionic liquids (ILs), the accurate determination of the physiochemical properties plays a pertinent role. Thermodynamic studies can provide an understanding into the nature of intermolecular interactions occurring between the solute and solvent in solutions. To this effect, thermodynamic properties of binary mixtures of 1-Methyl-3-Phenylimidazolium Iodide [MPhlM][l] + Isopropyl Alcohol [C3H8O] have been studied over the concentration range of mole fraction 0–1. Density and viscosity of the pure ionic liquid (IL) and the binary systems were measured and calculated. These data have been used to calculate excess molar volumes, VmE, Excess viscosity, Δη, excess Gibbs free energy of activation of viscous flow, ∆G*E of each component in the mixtures. To derive the binary coefficients and the standard deviations, the results were fitted into the Redlich-Kister Polynomial equation. The experimental and calculated quantities were used to study the nature of intermolecular interactions between the binary mixtures of 1-Methyl-3-Phenylimidazolium Iodide [MPhlM][l] + Isopropyl Alcohol [C3H8O]. Several factors were discovered to have influenced the interactions. Positive excess molar volume (VmE) values reported were influenced by dipole-dipole and dipole-dipole induced interactions between unlike molecules, resulting in the contraction of the molar volumes of the mixtures. The viscosities were correlated with single parameter Grungberg-Nissan, Hind, Frenkel and Kendel- Monroe models.},
 year = {2022}
}

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TY  - JOUR
T1  - Interactions of Binary Mixtures of 1-Methyl-3-Phenylimidazolium Iodide [MPhlm][l] and Isopropyl Alcohol [C3H8O] at Varying Temperatures
AU  - Victoria Bennett
AU  - Nimibofa Ayawei
Y1  - 2022/08/17
PY  - 2022
N1  - https://doi.org/10.11648/j.ajpc.20221103.11
DO  - 10.11648/j.ajpc.20221103.11
T2  - American Journal of Physical Chemistry
JF  - American Journal of Physical Chemistry
JO  - American Journal of Physical Chemistry
SP  - 45
EP  - 51
PB  - Science Publishing Group
SN  - 2327-2449
UR  - https://doi.org/10.11648/j.ajpc.20221103.11
AB  - In potential engineering and process design applications of binary mixtures containing ionic liquids (ILs), the accurate determination of the physiochemical properties plays a pertinent role. Thermodynamic studies can provide an understanding into the nature of intermolecular interactions occurring between the solute and solvent in solutions. To this effect, thermodynamic properties of binary mixtures of 1-Methyl-3-Phenylimidazolium Iodide [MPhlM][l] + Isopropyl Alcohol [C3H8O] have been studied over the concentration range of mole fraction 0–1. Density and viscosity of the pure ionic liquid (IL) and the binary systems were measured and calculated. These data have been used to calculate excess molar volumes, VmE, Excess viscosity, Δη, excess Gibbs free energy of activation of viscous flow, ∆G*E of each component in the mixtures. To derive the binary coefficients and the standard deviations, the results were fitted into the Redlich-Kister Polynomial equation. The experimental and calculated quantities were used to study the nature of intermolecular interactions between the binary mixtures of 1-Methyl-3-Phenylimidazolium Iodide [MPhlM][l] + Isopropyl Alcohol [C3H8O]. Several factors were discovered to have influenced the interactions. Positive excess molar volume (VmE) values reported were influenced by dipole-dipole and dipole-dipole induced interactions between unlike molecules, resulting in the contraction of the molar volumes of the mixtures. The viscosities were correlated with single parameter Grungberg-Nissan, Hind, Frenkel and Kendel- Monroe models.
VL  - 11
IS  - 3
ER  -

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